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According to the United States Census Bureau, the city has a total area of 25.6 square miles (66 square kilometres), of which 25.1 square miles (65 square kilometres) is land and 0.6 square miles (1.6 square kilometres) (2.15%) water.
The city stands at the northeast corner of the Finger Lakes region.
The Syracuse Solvay plant was the incubator for a large chemical industry complex owned by Allied Signal in Syracuse, the result of which made Onondaga Lake the most polluted in the nation.
The salt industry declined after the Civil War, but a new manufacturing industry arose in its place.
World War II sparked significant industrial expansion in the area: specialty steel, fasteners, custom machining.
In 1861, he developed the ammonia-soda process for the manufacture of soda ash (anhydrous sodium carbonate, a rare chemical called natrite, to distinguish it from natural natron of antiquity) from brine wells dug in the southern end of Tully valley (as a source of sodium chloride) and limestone (as a source of calcium carbonate).
The process was an improvement over the earlier Leblanc process.
General Electric moved its television manufacturing operations to Suffolk, Virginia, and later to Asia.
The Carrier Corporation moved its headquarters out of Syracuse, relocated its manufacturing operations out of state, and outsourced some of its production to Asian facilities.